Paper Titles

Rubber Processing Effluent Treatment with Chitosan: A Natural Biopolymer in Comparison with a Synthetic Coagulant
p.1

Morphological and Structural Properties of Porous Silicon (PSi)
p.11

Photocatalytic Degradation of a Basic Dye Using Zinc Oxide Nanocatalyst
p.18

Interaction of Dyes with Cationic Surfactants in Solutions: Determination of Critical Micelle Concentration
p.27

HomeInternational Letters of Chemistry, Physics and...International Letters of Chemistry, Physics and...Interaction of Dyes with Cationic Surfactants in...

Interaction of Dyes with Cationic Surfactants in Solutions: Determination of Critical Micelle Concentration

Article Preview

Abstract:

Interactions of sulforhodamine B or ethyl eosin (as the anionic dye) with cetylpyridinium bromide (as a cationic surfactant) have been investigated by visible spectroscopy in aqueous solution. The object of research is the association between an anion of dye and of cationic surfactant in aqueous solutions and its features. Computer simulation of these interactions was carried out with the use of AM1 and PM3 semi-empirical methods. A new spectrophotometric method was developed for determination of critical micelle concentration of cationic surfactants.

By email View Pdf

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 81)

Pages:

27-34

DOI:

https://doi.org/10.56431/p-3h14to

Citation:

Cite this paper

Online since:

February 2019

Authors:

Serghey Shapovalov*, V. Ponomariov

Keywords:

Cetylpyridinium Bromide, Critical Micelle Concentration, Dyes, Ethyl Eosin, Solution, Spectroscopy, Sulforhodamine B, Surfactants

Export:

RIS, BibTeX

Permissions:

Creative Commons CC BY 4.0

Share:

Citation:

* - Corresponding Author

[1] S.A. Shapovalov, The association processes of protolytic forms of dyes in solutions. Dissimilar association, Kharkiv National University, Kharkiv, Ukraine, 2014. (in Ukrainian) ISBN 978-966-2445-78-7.

[2] B. Heyne, Self-assembly of organic dyes in supramolecular aggregates, Photochemical & Photobiological Sciences. 15 (2016) 1103–1114.

DOI: 10.1039/c6pp00221h

[3] S.A. Shapovalov, Processes of self-association of dyes in solutions, Academic Publishing of European Union, OmniScriptum Publishing group, Riga, Latvia, 2018. ISBN 978-613-9-82294-2.

[4] M.S. Kumar, S. Dash, Effect of salts on micellization and clouding behavior of Pluronic F108 in aqueous solution using Trypan blue dye, Surfaces and Interfaces. 12 (2018) 1–7.

DOI: 10.1016/j.surfin.2018.04.001

[5] M. Mobarak et al., A superior adsorbent of CTAB/H2O2 solution−modified organic carbon rich-clay for hexavalent chromium and methyl orange uptake from solutions. 259 (2018) 384–397.

DOI: 10.1016/j.molliq.2018.02.014

[6] W. Ahmad et al., Enhancing sensitivity by Triton X-100 in extractive spectrophotometric determination of chromium via transforming the formed binary complex ion associate between chromate and rhodamine 6G into an adduct, Journal of Molecular Liquids. 261 (2018) 225–231.

DOI: 10.1016/j.molliq.2018.04.013

[7] M. Kaul, C.M. Barbieri, D.S. Pilch, Fluorescence-based approach for detecting and characterizing antibiotic-induced conformational changes in ribosomal RNA: Comparing aminoglycoside binding to prokaryotic and eukaryotic ribosomal RNA sequences, Journal of the American Chemical Society. 126(11) (2004) 3447–3453.

DOI: 10.1021/ja030568i

[8] M. López et al., Importance of hydrophobic interactions in the single-chained cationic surfactant-DNA complexation, Journal of Colloid and Interface Science. 521 (2018) 197–205.

DOI: 10.1016/j.jcis.2018.03.048

[9] S.A. Shapovalov, Ya.S. Kiseliova, Association of thymolsulfonephthalein and cresolsulfonephthalein anions with cationic cyanines in aqueous solution, Chemistry & Chemical Technology. 4 (2010) 271–276.

DOI: 10.23939/chcht04.04.271

[10] S.A. Shapovalov, Heteroassociates of singly- and doubly-charged anions of alizarin red S with the pinacyanol cation, Russian Chemical Bulletine. 60(1) (2011) 89–98.

DOI: 10.1007/s11172-011-0012-3

[11] V.I. Larin, S.A. Shapovalov, Association between complex ferrumcyanide anions with pinacyanol cation in aqueous solution, Chemistry & Chemical Technology. 6 (2012) 25–29.

DOI: 10.23939/chcht06.01.025

[12] A. Ali, S. Uzair, U. Farooq, Interactions of cationic, anionic and nonionic surfactants with cresol red dye in aqueous solutions: Conductometric, tensiometric, and spectroscopic studies, Tenside, Surfactants, Detergents. 54(4) (2017) 342–352.

DOI: 10.3139/113.110509

[13] S.A. Shapovalov, Cation-anionic association of organic dyes in aqueous solutions: structure and properties of associates, Modern Organic Chemistry Research. 2 (2017) 195–203.

DOI: 10.22606/mocr.2017.24006

[14] H. Lin et al., Interactions between bromophenol blue and cetyl- trimethylammonium bromide in aqueous solutions and microemulsions, Journal of Dispersion Science and Technology. 38(10) (2017) 1410–1414.

DOI: 10.1080/01932691.2016.1250215

[15] J. Guo et al., Interaction between Coomassie brilliant blue G250 and octylphenol polyoxyethylene ether (10) in aqueous solution, Journal of Dispersion Science and Technology. 39(8) (2018) 1208–1213.

DOI: 10.1080/01932691.2017.1388180

[16] S.A. Shapovalov, Association of quinaldine red cation in an aqueous solution: the interaction with anionic dyes, AASCIT Journal of Nanoscience. 3 (2017) 35–40.

[17] P.C.D.S. Pereira et al., Photophysical properties and interaction studies of Rose Bengal derivatives with biomimetic systems based in micellar aqueous solutions, Journal of Molecular Liquids. 230 (2017) 674–685.

DOI: 10.1016/j.molliq.2017.01.055

[18] N. Wang et al., Spectroscopic studies of sodium dodecyl sulfate and Sudan red III associations in solutions, AATCC Journal of Research. 4 (2017) 16–21.

DOI: 10.14504/ajr.4.4.3

[19] S.A. Shapovalov, Y.A. Svishchova, Heteroassociates of pinacyanol cation in aqueous solutions: formation and their interaction with organic multiply charged anions, French-Ukrainian Journal of Chemistry. 6(1) (2018) 21–30.

DOI: 10.17721/fujcv6i1p21-30

[20] Z. Wang et al., Transport of reactive X-3B dye at the interface between cationic surfactant-modified water-quenched blast furnace slag and aqueous solution, Canadian Journal of Chemical Engineering. 96(6) (2018) 1240–1249.

DOI: 10.1002/cjce.23105

[21] L. Deng et al., Sodium dodecyl sulfate intercalated and acrylamide anchored layered double hydroxides: A multifunctional adsorbent for highly efficient removal of Congo red, Journal of Colloid and Interface Science. 521 (2018) 172–182.

DOI: 10.1016/j.jcis.2018.03.040

[22] M. Chen, C.T. Jafvert, Application of cross-linked stearic acid nanoparticles with dialysis membranes for methylene blue recovery, Separation and Purification Technology. 204 (2018) 21–29.

DOI: 10.1016/j.seppur.2018.04.053

[23] Y. Zhou et al., A novel amphoteric β-cyclodextrin-based adsorbent for simultaneous removal of cationic/anionic dyes and bisphenol A, Chemical Engineering Journal. 341 (2018) 47–57.

DOI: 10.1016/j.cej.2018.01.155

[24] N.O. Mchedlov–Petrossyan et al., A new application of rhodamine 200B (sulforhodamine B), Dyes and Pigments. 28 (1995) 7–18.

DOI: 10.1016/0143-7208(94)00058-a

[25] H. Xirong et al., Determination of the critical micelle concentration of cationic surfactants, Journal of Chemical Education. 76(1) (1999) 93.

[26] B. Gohain, R.K. Dutta, Premicellar and micelle formation behavior of dye surfactant ion pairs in aqueous solutions, Journal of Colloid and Interface Science. 323(2) (2008) 395–402.

DOI: 10.1016/j.jcis.2008.02.063

[27] M. Rashidi-Alavijeh et al., Intermolecular interactions between a dye and cationic surfactants, Colloids and Surfaces. 380 (2011) 119–127.

DOI: 10.1016/j.colsurfa.2011.02.011

[28] Hypercube Products [Online]. Available: http://www.hyper.com/Products/tabid/354/Default.aspx.

[29] S.A. Shapovalov et al., Association of indopolymethine cyanine cations with anions of sulfonephthalein and xanthene dyes in water, Journal of the Brazilian Chemical Society. 16(2) (2005) 232–240.

DOI: 10.1590/s0103-50532005000200017

[30] S.A. Shapovalov, E.A. Samoilov, Regularities of homo- and heteroassociation of the pinacyanol cation in aqueous solution, Russian Chemical Bulletin. 57(7) (2008) 1405–1415.

DOI: 10.1007/s11172-008-0183-8

[31] M.J.S. Dewar, D.M. Storch, Development and use of quantum molecular models. 75. Comparative tests of theoretical procedures for studying chemical reactions, Journal of the American Chemical Society. 107(13) (1985) 3898–3902.

DOI: 10.1021/ja00299a023